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Bases. Bases are proton acceptor. The concept of the hydroxide ion is very important to understand how bases work. How water behaves introduces the hydroxide ion. All bases produce the hydroxide ion. If we were to replace one of the Hydrogen atoms in water (HOH) with a Sodium atom, we would end up with the molecule Sodium Hydroxide (NaOH). A molecule of NaOH is shown below. The Hydrogen is sharing an electron with a P orbital of Oxygen. And the Sodium is sharing an electron with a P orbital of Oxygen. If we were to put NaOH in water, the Sodium would separate from the hydroxide ion. The Oxygen really likes having the electron from the Sodium. So if the Sodium decided to leave, there would be a tug of war for the electron. The electronegativity for Oxygen is 3.5. And the electronegativity for Sodium is 0.9. Oxygen is stronger than Sodium. The Oxygen would win the tug of war and keep the electron. So now the hydroxide ion is floating around in the water by itself. And the Sodium+ is floating around in the water by itself. Adding NaOH to water will turn the pH to basic. |
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